4-Chloro-N-(3,4-dichlorophenyl)-2-methylbenzenesulfonamide
نویسندگان
چکیده
In the title compound, C(13)H(10)Cl(3)NO(2)S, the N-C bond in the C-SO(2)-NH-C segment forms trans and gauche torsion angles with respect to the S=O bonds. Further, the N-H bond in the C-SO(2)-NH-C segment is anti to the meta-Cl atom in the anilino benzene ring and nearly syn with respect to the ortho-methyl group in the sulfonyl benzene ring. The C-SO(2)-NH-C torsion angle is -49.4 (2)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 54.6 (1)°. In the crystal, mol-ecules are linked into chains along the c-axis direction by inter-molecular N-H⋯O hydrogen bonds.
منابع مشابه
N-(3,4-Dichlorophenyl)-4-methylbenzenesulfonamide
In the title compound, C(13)H(11)Cl(2)NO(2)S, the conformation of the N-C bond in the C-SO(2)-NH-C segment has gauche torsions with respect to the S=O bonds. The mol-ecule is bent at the S atom with a C-SO(2)-NH-C torsion angle of 64.3 (4)°. Furthermore, the conformation of the N-H bond and the meta-chloro group in the adjacent benzene ring are anti to each other. The two benzene rings are tilt...
متن کامل4-Chloro-N-(3,5-dichlorophenyl)-2-methylbenzenesulfonamide
In the title compound, C(13)H(10)Cl(3)NO(2)S, torsion angle of the C-SO(2)-NH-C group in the mol-ecule is -58.57 (26)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 84.2 (1)°. The crystal structure features inversion-related dimers linked by pairs of N-H⋯O hydrogen bonds.
متن کامل4-Chloro-N-(2,3-dichlorophenyl)-2-methylbenzenesulfonamide
The torsion angle of the C-SO(2)-NH-C moiety in the title compound, C(13)H(10)Cl(3)NO(2)S, is 50.4 (2)°. The sulfonyl and aniline benzene rings are tilted relative to each other by 69.6 (1)°. The crystal structure is stabilized by N-H⋯O hydrogen bonds, linking the mol-ecules into zigzag chains parallel to the b axis.
متن کاملN-(2,5-Dichlorophenyl)-4-methylbenzenesulfonamide
In the title compound, C(13)H(11)Cl(2)NO(2)S, the N-C bond in the C-SO(2)-NH-C segment has gauche torsion angles with respect to the S=O bonds. The mol-ecule is bent at the S atom with an C-SO(2)-NH-C torsion angle of 62.1 (2)°. Furthermore, the conformation of the N-H bond is syn to the ortho-chloro group in the adjacent benzene ring. The benzene rings are tilted by 67.8 (1)° relative to each ...
متن کامل1-Chloro-4-(3,4-dichlorophenyl)-3,4-dihydronaphthalene-2-carbaldehyde
The title compound, C(17)H(11)Cl(3)O, was synthesized via the Vilsmeier-Haack reaction. The dihydro-naphthalene ring system is non-planar, the dihedral angle between the two fused rings being 10.87 (13)°; it forms a dihedral angle of 81.45 (10)° with the dichloro-phenyl ring. The crystal structure features inter-molecular C-H⋯O hydrogen bonds.
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